Crystal structure approach of the disordered new compounds Bi∼1.2M∼1.2PO5.5 (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates
Identifieur interne : 000258 ( France/Analysis ); précédent : 000257; suivant : 000259Crystal structure approach of the disordered new compounds Bi∼1.2M∼1.2PO5.5 (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates
Auteurs : F. Abraham [France] ; O. Cousin [France] ; O. Mentre [France] ; El M. Ketatni [Maroc]Source :
- Journal of solid state chemistry [ 0022-4596 ] ; 2002.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Préparation chimique, Réaction état solide, Diffraction RX, Structure cristalline, Cristal désordonné, Structure fluorite, Cobalt oxyde, Cobalt phosphate, Manganèse oxyde, Manganèse phosphate, Bismuth oxyde, Bismuth Phosphate, Susceptibilité magnétique, Bi Co O P, 6166F, Oxyphosphate, Bi1,2Mn1,2PO5,5, Bi1,2Co1,2PO5,5, Bi Mn O P.
English descriptors
- KwdEn :
Abstract
The crystal structures of some recently published bismuth-transition metal oxy-phosphates are described as the association of complex infinite one-dimensional polycations and phosphate anions. The complex cations are built from oxygen-centered tetrahedra sharing edges to form infinite ribbons of n tetrahedra width. This structural concept allows one to describe the essential structural features of new highly disordered bismuth-transition metal oxy-phosphates, Bi∼1.2M∼1.2PO5.5 (M = Mn, Co, Zn). The new compounds have been synthesized and structurally characterized by single-crystal X-ray diffraction. The three compounds crystallize in the orthorhombic space group Ibam (No. 72), Z=8. The lattice parameters are a = 15.079(2), b = 11.247(2), c = 5.437(1) Å for M = Mn, a = 14.752(3), b = 11.205(3), c = 5.434(2) Å for M = Co and a = 14.809(2), b = 11.214(1), c = 5.440(1) Å for M = Zn. Because of a high disorder over several cationic sites, only an approach of the crystal structure determination has been achieved. Actually, the structure is characterized by perfectly defined ribbons parallel to the (010) plane and built from a central chain of edge-shared OBi4 tetrahedra running along the c axis and linked by edges to two other edge-shared O(Bi,M)4 tetrahedra chains. The positions at the border of ribbons are randomly occupied by bismuth and M atoms. The formula of the three tetrahedra width ribbons is (O3Bi2.4M1.6)+4.4. The phosphate ions and M2+ cations are disordered in the interspace between the ribbons.
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PascalFrancis, to step Corpus: 000244
- to stream PascalFrancis, to step Curation: 000051
- to stream PascalFrancis, to step Checkpoint: 000256
- to stream Main, to step Merge: 000B56
- to stream Main, to step Curation: 000B39
- to stream Main, to step Exploration: 000B39
- to stream France, to step Extraction: 000258
Links to Exploration step
Pascal:02-0529086Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Crystal structure approach of the disordered new compounds Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates</title><author><name sortKey="Abraham, F" sort="Abraham, F" uniqKey="Abraham F" first="F." last="Abraham">F. Abraham</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Cousin, O" sort="Cousin, O" uniqKey="Cousin O" first="O." last="Cousin">O. Cousin</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Mentre, O" sort="Mentre, O" uniqKey="Mentre O" first="O." last="Mentre">O. Mentre</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Ketatni, El M" sort="Ketatni, El M" uniqKey="Ketatni E" first="El M." last="Ketatni">El M. Ketatni</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie et Chimie des Matériaux, Faculté des Sciences, Université Cadi Ayyad, B.P. 523</s1><s2>Beni Mellal</s2><s3>MAR</s3><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>Beni Mellal</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">02-0529086</idno><date when="2002">2002</date><idno type="stanalyst">PASCAL 02-0529086 INIST</idno><idno type="RBID">Pascal:02-0529086</idno><idno type="wicri:Area/PascalFrancis/Corpus">000244</idno><idno type="wicri:Area/PascalFrancis/Curation">000051</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000256</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000256</idno><idno type="wicri:doubleKey">0022-4596:2002:Abraham F:crystal:structure:approach</idno><idno type="wicri:Area/Main/Merge">000B56</idno><idno type="wicri:Area/Main/Curation">000B39</idno><idno type="wicri:Area/Main/Exploration">000B39</idno><idno type="wicri:Area/France/Extraction">000258</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Crystal structure approach of the disordered new compounds Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates</title><author><name sortKey="Abraham, F" sort="Abraham, F" uniqKey="Abraham F" first="F." last="Abraham">F. Abraham</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Cousin, O" sort="Cousin, O" uniqKey="Cousin O" first="O." last="Cousin">O. Cousin</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Mentre, O" sort="Mentre, O" uniqKey="Mentre O" first="O." last="Mentre">O. Mentre</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Ketatni, El M" sort="Ketatni, El M" uniqKey="Ketatni E" first="El M." last="Ketatni">El M. Ketatni</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie et Chimie des Matériaux, Faculté des Sciences, Université Cadi Ayyad, B.P. 523</s1><s2>Beni Mellal</s2><s3>MAR</s3><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>Beni Mellal</wicri:noRegion></affiliation></author></analytic><series><title level="j" type="main">Journal of solid state chemistry</title><title level="j" type="abbreviated">J. solid state chem.</title><idno type="ISSN">0022-4596</idno><imprint><date when="2002">2002</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal of solid state chemistry</title><title level="j" type="abbreviated">J. solid state chem.</title><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bismuth Phosphates</term><term>Bismuth oxides</term><term>Chemical preparation</term><term>Cobalt oxides</term><term>Cobalt phosphates</term><term>Crystal structure</term><term>Disordered crystals</term><term>Experimental study</term><term>Fluorite structure</term><term>Magnetic susceptibility</term><term>Manganese oxides</term><term>Manganese phosphates</term><term>Solid state reaction</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Préparation chimique</term><term>Réaction état solide</term><term>Diffraction RX</term><term>Structure cristalline</term><term>Cristal désordonné</term><term>Structure fluorite</term><term>Cobalt oxyde</term><term>Cobalt phosphate</term><term>Manganèse oxyde</term><term>Manganèse phosphate</term><term>Bismuth oxyde</term><term>Bismuth Phosphate</term><term>Susceptibilité magnétique</term><term>Bi Co O P</term><term>6166F</term><term>Oxyphosphate</term><term>Bi1,2Mn1,2PO5,5</term><term>Bi1,2Co1,2PO5,5</term><term>Bi Mn O P</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The crystal structures of some recently published bismuth-transition metal oxy-phosphates are described as the association of complex infinite one-dimensional polycations and phosphate anions. The complex cations are built from oxygen-centered tetrahedra sharing edges to form infinite ribbons of n tetrahedra width. This structural concept allows one to describe the essential structural features of new highly disordered bismuth-transition metal oxy-phosphates, Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M = Mn, Co, Zn). The new compounds have been synthesized and structurally characterized by single-crystal X-ray diffraction. The three compounds crystallize in the orthorhombic space group Ibam (No. 72), Z=8. The lattice parameters are a = 15.079(2), b = 11.247(2), c = 5.437(1) Å for M = Mn, a = 14.752(3), b = 11.205(3), c = 5.434(2) Å for M = Co and a = 14.809(2), b = 11.214(1), c = 5.440(1) Å for M = Zn. Because of a high disorder over several cationic sites, only an approach of the crystal structure determination has been achieved. Actually, the structure is characterized by perfectly defined ribbons parallel to the (010) plane and built from a central chain of edge-shared OBi<sub>4</sub> tetrahedra running along the c axis and linked by edges to two other edge-shared O(Bi,M)<sub>4</sub> tetrahedra chains. The positions at the border of ribbons are randomly occupied by bismuth and M atoms. The formula of the three tetrahedra width ribbons is (O<sub>3</sub>Bi<sub>2.4</sub>M<sub>1.6</sub>)<sup>+4.4</sup>. The phosphate ions and M<sup>2+</sup> cations are disordered in the interspace between the ribbons.</div></front></TEI><affiliations><list><country><li>France</li><li>Maroc</li></country><region><li>Hauts-de-France</li><li>Nord-Pas-de-Calais</li></region><settlement><li>Villeneuve d'Ascq</li></settlement></list><tree><country name="France"><region name="Hauts-de-France"><name sortKey="Abraham, F" sort="Abraham, F" uniqKey="Abraham F" first="F." last="Abraham">F. Abraham</name></region><name sortKey="Cousin, O" sort="Cousin, O" uniqKey="Cousin O" first="O." last="Cousin">O. Cousin</name><name sortKey="Mentre, O" sort="Mentre, O" uniqKey="Mentre O" first="O." last="Mentre">O. Mentre</name></country><country name="Maroc"><noRegion><name sortKey="Ketatni, El M" sort="Ketatni, El M" uniqKey="Ketatni E" first="El M." last="Ketatni">El M. Ketatni</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/France/Analysis
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000258 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 000258 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= CobaltMaghrebV1
|flux= France
|étape= Analysis
|type= RBID
|clé= Pascal:02-0529086
|texte= Crystal structure approach of the disordered new compounds Bi∼1.2M∼1.2PO5.5 (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates
}}
| This area was generated with Dilib version V0.6.32. |  |